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Recent Advances in The Smiles Rearrangement: New Opportunities for Arylation
Whalley,
David M.;
Greaney,
Michael
F.
Review Article
Synthesis
, 2022; 54(08): 1908-1918
Truce‐Smiles Rearrangements via Strain‐Release: Harnessing Primary Alkyl Radicals for Metal‐Free Arylation
Whalley,
David M.;
Seayad,
Jayasree;
Greaney,
Michael
F.
Angew. Chem. Int. Ed.
2021, 60, 22219 –22223
Programmable late-stage C−H bond functionalization enabled by integration of enzymes with chemocatalysis
Craven, Elliott J.; Latham,
Jonathan;
Shepherd, Sarah A.; Khan,
Imtiaz;
Diaz-Rodriguez,
Alba;
Greaney,
Michael F.;
Micklefield,
Jason
Nat. Catal.
, 2021, 4, 385–394
Integrated Electro‐Biocatalysis for Amine Alkylation with Alcohols
Peñafiel, Itziar; Dryfe, Robert A. W.; Turner,
Nicholas J.;
Greaney, Michael F.
C
hemCatChem,
2021, 13, 864–867
A Visible Light-Mediated, Decarboxylative, Desulfonylative Smiles Rearrangement for General Arylethylamine Syntheses
Whalley, David M.; Duong, Hung. A.; Greaney, Michael F.
Chem. Commun
.,
2020,56, 11493-11496
ortho
C-H Arylation of Arenes at Room Temperature Using Visible Light Ruthenium C-H Activation
Sagadevan, Arunachalam; Charitou, Anastasios
;
Wang, Fen; Ivanova, Maria; Vuagnat, Martin; Greaney, Michael F.
Chem. Sci.
, 2020,
11, 4439-4443
α-Fluorination of Nitrobenzenes and Nitropyridines via Vicarious Nucleophilic Substitution of Hydrogen
Al-Mkhaizim, Fayez; Greaney, Michael F.
Synlett
, 2020,
31(11): 1094-1096
Arylation and Alkenylation of Activated Alkyl Halides Using Sulfonamides
Johnson, Stuart; Kovacs, Ervin; Greaney, Michael F.
Chem. Commun.,
2020, 56, 3222-3224
Arylation Using Sulfonamides: Phenylacetamide Synthesis through Tandem Acylation-Smiles Rearrangement
Barlow, Helen L.; Rabet, Pauline T. G.; Durie, Alastair; Evans, Tim; Greaney, Michael F.
Org. Lett.,
2019, 21, 9033-9035
meta
-Selective C-H Activation of Arenes at Room Temperature Using Visible Light: Dual-Function Ruthenium Catalysis
Sagadevan, Arunachalam; Greaney, Michael F.
Angew. Chem. Int. Ed.,
2019, 58, 9826-9830
Alkene Carboarylation through Catalyst-Free, Visible Light-Mediated Smiles Rearrangement
Whalley, David M.; Duong, Hung A.; Greaney, Michael F.
Chem. Eur. J.,
2019, 25, 1927-1930
Concurrent Biocatalytic Oxidation and C-C Bond Formation via Gold Catalysis: One-Pot Alkynylation of N-Alkyl Tetrahydroisoquinolines
Odachowski, Marcin; Greaney, Michael F.; Turner, Nicholas J.
ACS Catal.,
2018, 8, 10032-10035
Ruthenium-Catalyzed meta-Carboxylation
Barlow, Helen L.; Teskey, Christopher J.; Greaney, Michael F.
Org. Lett.,
2017, 19, 6662-6665
Synthesis of Triarylamines via Sequential C-N Bond Formation
Modha, Sachin G.; Popescu, Mihai V.; Greaney, Michael F.
J. Org. Chem.,
2017, 82, 11933-11938
RadH: A Versatile Halogenase for Integration into Synthetic Pathways
Menon, Binuraj R. K.; Brandenburger, Eileen; Sharif, Humera H.; Klemstein, Ulrike; Shepherd, Sarah A.; Greaney, Michael F.; Micklefield, Jason
Angew. Chem. Int. Ed.,
2017, 56, 11841-11845
Modern Aspects of the Smiles Rearrangement
Holden, Catherine M.; Greaney, Michael F.
Chem. Eur. J.,
2017, 23, 8992-9008
Domino
N
-/
C
-Arylation via In Situ Generation of a Directing Group: Atom-Efficient Arylation Using Diaryliodonium Salts
Teskey, Christopher J.; Sohel, Shariar M. A.; Bunting, Danielle L.; Modha, Sachin G.; Greaney, Michael F.
Angew. Chem. Int. Ed.,
2017, 56, 5263-5266
Metal-Free Intermolecular Aminoarylation of Alkynes
Rabet, Pauline T. G.; Boyd, Scott; Greaney, Michael F.
Angew. Chem. Int. Ed.,
2017, 56, 4183-4186
An Engineered Tryptophan Synthase Opens New Enzymatic Pathways to β-Methyltryptophan and Derivatives
Francis, Daniel; Winn, Michael; Latham, Jonathan; Greaney, Michael F.; Micklefield, Jason
ChemBioChem,
2017, 18, 382-386
Cross-Dehydrogenative-Coupling of Alkoxybenzenes with Toluenes: Copper(II) Halide Mediated Tandem Halo/Benzylation of Arenes
Storr, Thomas E.; Teskey, Christopher J.; Greaney, Michael F.
Chem. Eur. J.,
2016, 22, 18169-18178
Synthesis of Biaryls Using Aryne Intermediates
Garcia-Lopez, Jose-Antonio; Greaney, Michael F.
Chem. Soc. Rev.,
2016, 45, 6766-6798
Structure and Biocatalytic Scope of Thermophilic Flavin-Dependent Halogenase and Flavin Reductase Enzymes
Menon, Binuraj R. K.; Latham, Jonathan; Dunstan, Mark S.; Brandenburger, Eileen; Klemstein, Ulrike; Leys, David; Karthikeyan, Chinnan; Greaney, Michael F.; Shepherd, Sarah A.; Micklefield, Jason
Org. Biomol. Chem.,
2016, 14, 9354-9361
Integrated Catalysis Opens New Arylation Pathways via Regiodivergent Enzymatic C-H Activation
Latham, Jonathan; Henry, Jean-Marc; Sharif, Humera H.; Menon, Binuraj R. K.; Shepherd, Sarah A.; Greaney, Michael F.; Micklefield, Jason
Nat. Commun.
, 2016, 7, 11873
Benzylic C-H Azidation Using the Zhdankin Reagent and a Copper Photoredox Catalyst
Rabet, Pauline T. G.; Fumagalli, Gabriele; Boyd, Scott; Greaney, Michael F.
Org. Lett.,
2016, 18, 1646-1649
Metal Free Bi(hetero)aryl Synthesis: A Benzyne Truce-Smiles Rearrangement
Holden, Catherine M.; Sohel, Shariar M. A.; Greaney, Michael F.
Angew. Chem. Int. Ed.,
2016, 55, 2450-2453
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